Superdurable Bifunctional Oxygen Electrocatalyst for High-Performance Zinc–Air Batteries

The development of high-efficiency and durable bifunctional electrocatalysts for both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical for the widespread application of rechargeable zinc-air (Zn-air) batteries. This calls for rational screening of targeted ORR/OER components and precise control of their atomic and electronic structures to produce synergistic effects. Here, we report a Mn-doped RuO₂ (Mn-RuO₂) bimetallic oxide with atomic-scale dispersion of Mn atoms into the RuO₂ lattice, which exhibits remarkable activity and super durability for both the ORR and OER, with a very low potential difference (ΔE) of 0.64 V between the half-wave potential of ORR (E_1/2) and the OER potential at 10 mA cm^-2 (E_j10) and a negligible decay of E_1/2 and E_j10 after 250 000 and 30 000 CV cycles for ORR and OER, respectively. Moreover, Zn-air batteries using the Mn-RuO₂ catalysts exhibit a high power density of 181 mW cm^-2, low charge/discharge voltage gaps of 0.69/0.96/1.38 V, and ultralong lifespans of 15 000/2800/1800 cycles (corresponding to 2500/467/300 h operation time) at a current density of 10/50/100 mA cm^-2, respectively. Theoretical calculations reveal that the excellent performances of Mn-RuO₂ is mainly due to the precise optimization of valence state and d-band center for appropriate adsorption energy of the oxygenated intermediates.