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[求助补充材料]
Te-Cu dual adsorption-conversion function cathode enables high-energy-density and long-lifespan liquid metal batteries 相关领域
法拉第效率
阴极
材料科学
吸附
溶解
锂(药物)
储能
光电子学
金属
液态金属
过渡金属
金属锂
化学工程
电极
电流密度
工作职能
纳米技术
磷酸铁锂
阳极
工作(物理)
化学
电化学
容量损失
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Liquid metal batteries (LMBs) are an attractive large-scale energy storage technology due to their ultra-long service life, high safety, and exceptionally low comprehensive cost. Te-based LMBs are regarded as one of the most promising directions for developing high-energy-density LMBs. However, their practical application is still hindered by low Coulombic efficiency and short cycle life, primarily due to the shuttle effect induced by the dissolution of reaction products. Herein, the strategy of employing transition metal (Cu) with strong polar in teractions with lithium polytellurides as the alloying element to construct cathode is proposed. Benefiting from the strong adsorption and conversion-promoting capabilities of in-situ generated metal tellurides (CuTe and Cu4Te3) towards lithium polytellurides, the shuttle effect is significantly suppressed. |
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(2025-6-4)