纳米复合材料
光催化
材料科学
异质结
甲基橙
可见光谱
光致发光
降级(电信)
化学工程
光化学
分解水
纳米技术
光电子学
催化作用
有机化学
化学
电信
计算机科学
工程类
作者
Deli Jiang,Jie Li,Chaosheng Xing,Zhengyuan Zhang,Suci Meng,Min Chen
标识
DOI:10.1021/acsami.5b05118
摘要
Design and exploitation of efficient visible light photocatalytic systems for water splitting and degradation of organic dyes are of huge interest in the fields of energy conversion and environmental protection. Herein, two-dimensional CaIn2S4/g-C3N4 heterojunction nanocomposites with intimate interfacial contact have been synthesized by a facile two-step method. Compared with pristine g-C3N4 and CaIn2S4, the CaIn2S4/g-C3N4 heterojunction nanocomposites exhibited significantly enhanced H2 evolution and photocatalytic degradation of methyl orange (MO) activities under visible light irradiation. The optimal CaIn2S4/g-C3N4 nanocomposite shows a H2 evolution rate of 102 μmol g–1 h–1, which is more than 3 times that of pristine CaIn2S4. The mechanisms for improving the photocatalytic performance of the CaIn2S4/g-C3N4 nanocomposites were proposed by using the photoluminescence measurement and electrochemical analyses. It was demonstrated that the enhanced photocatalytic performance of CaIn2S4/g-C3N4 heterojunction nanocomposites mainly stems from the enhanced charge separation efficiency. In addition, a plausible mechanism for the degradation of MO dye over CaIn2S4/g-C3N4 nanocomposites is also elucidated using active species scavenger’s studies.
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