石墨烯
材料科学
阳极
石墨氮化碳
复合数
氧化物
化学工程
钠离子电池
电化学
煅烧
介孔材料
碳纤维
复合材料
纳米技术
电极
法拉第效率
冶金
化学
有机化学
物理化学
催化作用
工程类
光催化
作者
Anupam Patel,Himani Gupta,Shri Singh,Nitin Srivastava,Raghvendra Mishra,Dipika Meghnani,Rupesh K. Tiwari,Anurag Tiwari,Vimal K. Tiwari,Rajendra Kumar Singh
出处
期刊:FlatChem
[Elsevier]
日期:2022-05-01
卷期号:33: 100351-100351
被引量:6
标识
DOI:10.1016/j.flatc.2022.100351
摘要
A layered composite g-C3N4@RGO of graphitic carbon nitride (g-C3N4) and reduced graphene oxide (RGO) is reported as an anode material for rechargeable sodium ion batteries (SIBs). Initially, conducting interconnected hydrogel RGO was prepared by hydrothermal method and was further soaked in saturated urea solution, followed by calcination to synthesize g-C3N4@RGO composites. The coin type half cells were prepared by using composite g-C3N4@RGO and pristine RGO as anode and their electrochemical performances were compared. The prepared half-cell of the composite anode delivers maximum reversible specific discharge capacity of ∼ 170 mAh.g−1 and ∼ 160 mAh.g−1 at 0.1C and at 0.2C, respectively. Whereas, prepared half-cell using RGO anode shows maximum reversible discharge capacity of ∼ 146 mAh.g−1 and ∼ 133 mAh.g-1at 0.1C and 0.2C, respectively. This composite material g-C3N4@RGO shows excellent cyclability (2000 cycles) and columbic efficiency ∼ 100% with no capacity fading compared to the RGO. The binding of g-C3N4 with RGO prevents stacking of RGO sheets and provides macro and sub-micron porous structure for smooth intercalation and trapping of Na+-ions in composite g-C3N4@RGO anode during electrochemical cycling. The design of g-C3N4@RGO composite as a negative electrode improves the cell performance and offers effective strategy to develop low-cost and long cycle life SIBs.
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