氧化还原
镍
循环伏安法
微分脉冲伏安法
电子转移
材料科学
催化作用
碳纤维
无机化学
电化学
尿素
氮气
电极
阳极
分析化学(期刊)
化学
物理化学
冶金
有机化学
复合材料
复合数
作者
Narawee Asavakijthananont,Metini Janyasupab
出处
期刊:Key Engineering Materials
日期:2021-02-01
卷期号:877: 102-107
标识
DOI:10.4028/www.scientific.net/kem.877.102
摘要
A novel redox couple of metallic nickel (Ni) catalyst can become a great candidate of non-enzymatic detection. By taking advantage of fast electron transfer, Ni redox couples can be tailored as pseudo-enzyme in urea measurement. In this study, Ni catalyst on nitrogen doped carbon (Ni-NC) was synthesized and characterized morphological, elemental, and electrocatalytic properties in comparison to different configuration of pure nickel (Ni), Ni with carbon (Ni-C), and bare carbon electrode, assessed by cyclic voltammetry and differential pulse voltammetry. By examining various Ni redox couples in rapid electron transfer process, the prominent anodic and cathodic peaks of Ni 2+ /Ni 3+ were applicable to detect urea in the detection range of 1-20 mM, with an excellent sensitivity and relative standard deviation of 1.634 μA.mM -1 (R 2 of 0.989) and 4.89%, respectively. Therefore, Ni-NC can find practical applications for material sensing device toward non-enzymatic urea measurement.
科研通智能强力驱动
Strongly Powered by AbleSci AI