化学
充氧
电化学
激进的
催化作用
组合化学
氧化磷酸化
有机化学
电极
物理化学
生态学
生物化学
生物
作者
Jin‐Lin Wan,Jing‐Mei Huang
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-11-28
卷期号:24 (48): 8914-8919
被引量:15
标识
DOI:10.1021/acs.orglett.2c03774
摘要
An electrochemical oxidative sulfoximido-oxygenation of alkenes has been developed by using NH-sulfoximines and alcohols directly. This method proceeds regioselectively without metal catalysts and external chemical oxidants and shows broad substrate scope and diverse functional group compatibility. Based upon the preliminary mechanism studies, N-centered sulfoximidoyl radicals were involved in this electrochemical process.
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