Composite silica aerogel based on HNTs-modified APP with enhanced thermal insulation and flame retardancy performance for organosilicon resin

Efficient thermal insulation and flame-retardant materials are crucial in reducing energy consumption and minimizing fire hazards. This work presents a novel method for preparing a composite aerogel: a silane coupling agent was used as a chemical bridge to synthesize a new flame retardant AKH (modified APP with HNTs). AKH was incorporated into the silica sol to fabricate the SA-AKH composite aerogel. SA-AKH features a dense three-dimensional network skeletal structure, excellent thermal stability, and a high specific surface area. When integrated into organosilicon resin, SA-AKH significantly enhances the flame resistance of composite materials. During cone calorimetry testing (CCT), SSAKH4 exhibited a peak heat release rate (PHRR) of 281.88 kW/m2 and total smoke production (TSP) of 5.52 m2, representing a decrease of 30.8 % and 4.5 %, respectively, compared to SSA4. The composite material, derived from the unique mesoporous structure of aerogel combined with the flame retardant and hollow characterization of AKH, demonstrates exceptional flame retardancy and smoke suppression. SA-AKH is expected to make novel advancements in the field of high-efficiency insulation and flame-resistant composites.