荧光粉
X射线光电子能谱
发光
光致发光
分析化学(期刊)
衍射仪
热稳定性
结构精修
材料科学
兴奋剂
发射光谱
光致发光激发
离子
激发
发射强度
晶体结构
化学
谱线
光电子学
结晶学
核磁共振
物理
天文
有机化学
工程类
色谱法
电气工程
作者
Li Li,Xinji Li,Weidi Xia,Yongjie Wang,Faling Ling,Sha Jiang,Guotao Xiang,Xianju Zhou,Dengfeng Li,Yongbin Hua
标识
DOI:10.1016/j.jallcom.2022.164322
摘要
The sensing sensitivities of the Sr2InSbO6:Eu3+ phosphors with different doping concentrations were investigated based on the temperature-dependent decay curves. The crystal and electronic structure were studied by the X-ray diffractometer (XRD), Rietveld refinement, and X-ray photoelectron spectroscopy (XPS). In addition, the luminescent behaviors (e.g., photoluminescence spectra, concentration quenching, thermal stability, and luminescent dynamic) were investigated under the green light excitation (λex = 529 nm). The dominated peak was assigned to the 5D0 → 7F1 transition emitting an orange-red emission. Moreover, the obtained sample exhibited excellent thermal stability that the emission intensity remained 91.61% at 425 K. Eventually, the relative sensing sensitivity of the Sr2EuSbO6 phosphor was 0.766% K−1 and the doping concentration of Eu3+ ions greatly affected the sensing sensitivity. This work is the first time to investigate the single Eu3+-activated luminescent materials under the green light excitation.
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