Abstract The structures of the four new telluridoindates (II) (monoclinic, space group C2/c, Z = 4), (III) (monoclinic, P2 1 /c, Z = 4), (IV) (triclinic, P $\bar 1$ , Z = 2), and (V) (tetragonal, I $\bar 4$ m2, Z = 4) are determined by single crystal XRD.