佩多:嘘
材料科学
碳纳米管
热电效应
纳米复合材料
原位聚合
聚合
塞贝克系数
傅里叶变换红外光谱
化学工程
聚(3,4-亚乙基二氧噻吩)
透射电子显微镜
纳米技术
复合材料
聚合物
图层(电子)
热导率
物理
工程类
热力学
作者
Zhuang Zhang,Guangming Chen,Hanfu Wang,Xin Li
标识
DOI:10.1002/asia.201403100
摘要
Abstract A template‐directed in situ polymerization preparation of nanocomposites of poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)‐coated multi‐walled carbon nanotubes (MWCNTs) with greatly enhanced thermoelectric property is presented. The results reveal that monomeric 3,4‐ethylenedioxythiophene was successfully polymerized, enwrapping the surfaces of dispersed MWCNTs (templates) with the aid of PSS. The coated morphology was directly observed by high‐resolution transmission electron microscopy. The coated layer was further characterized by energy‐dispersive X‐ray spectroscopy and X‐ray diffraction. In addition, the interfacial interaction between PEDOT:PSS and MWCNTs was studied by Fourier transform infrared spectroscopy. Finally, the thermoelectric measurements show that the obtained PEDOT:PSS/MWCNT nanocomposites exhibited greatly enhanced electrical conductivities, Seebeck coefficients, and power factors when compared with those of neat PEDOT:PSS.
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