吸附
化学
扩散
标准摩尔熵
化学工程
吉布斯自由能
色谱法
热力学
有机化学
标准生成焓
物理
工程类
作者
Ying Yu,Yuan-Yi Zhuang,Zhonghua Wang,Mingqiang Qiu
出处
期刊:Chemosphere
[Elsevier BV]
日期:2004-01-01
卷期号:54 (3): 425-430
被引量:132
标识
DOI:10.1016/s0045-6535(03)00654-4
摘要
Adsorption behavior of five kinds of water-soluble dyes onto functionalized resin NKY has been dynamically and thermodynamically investigated. The results showed that the adsorption rates of dye K-GN, K-2BP, KN-R, AAB and 2G are all controlled by liquid film diffusion and particle diffusion. Equilibrium adsorption data can be well described by three-parameter equation. The first layer adsorption is the physical enhanced by chemical effect but multilayer adsorption is typically physical adsorption. Standard free energy change DeltaG(0) and standard entropy change DeltaS(0) indicate the adsorption of the dyes onto NKY can occur spontaneously.
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