三元运算
光催化
异质结
纳米颗粒
化学
制氢
纳米复合材料
化学工程
亚甲蓝
降级(电信)
氢
纳米技术
催化作用
材料科学
光电子学
有机化学
工程类
程序设计语言
电信
计算机科学
作者
Lan Wang,Hanghang Zhou,Hongzhong Zhang,Yali Song,Huan Zhang,Xuhui Qian
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2020-02-03
卷期号:59 (4): 2278-2287
被引量:60
标识
DOI:10.1021/acs.inorgchem.9b03007
摘要
It is challenging to design and prepare difunctional photocatalysts for simultaneous photocatalytic wastewater purification and hydrogen (H2) energy production. In this study, a novel ternary heterostructure pholocatalyst, ZnIn2S4@SiO2@TiO2 (ZIS@SiO2@TiO2) was successfully prepared by simple sol-gel and solvothermal methods. The SiO2 nanospheres were used as a support to prevent the aggregation of TiO2 nanoparticles efficiently. The SiO2@TiO2 nanoparticles were uniformly inserted into the 2D-layered flowerlike ZnIn2S4 to form a ternary heterostructure that can efficiently improve the separation and transportation of photoinduced electron-hole pairs. As expected, the 150%-ZIS@SiO2@TiO2 nanocomposite exhibited an excellent rate of H2 production under simulated sunlight (618.3 μmol g-1 h-1), which was 229 and 3.3 times higher than the binary SiO2@TiO2 nanoparticles and pure ZnIn2S4. Furthermore, the degradation efficiency of methylene blue reached 99.7% during the H2 production process. These findings provided possibilities to couple energy conversion with environmental restoration.
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