光催化
催化作用
化学
光化学
辐照
组合化学
有机化学
物理
核物理学
作者
Taiqiang Ye,Yuzheng Li,Yan Ma,Shenpeng Tan,Feng Li
标识
DOI:10.1021/acs.joc.3c02284
摘要
An efficient photocatalytic oxidation of benzylic C(sp3)–H bonds to ketones, esters, and amides has been developed using NBS as a metal-free photocatalyst and O2 as an oxidant. A variety of synthetically and biologically valuable compounds are assembled in moderate to excellent yields. The synthetic utility of this approach has been demonstrated by gram-scale experiments. A possible free radical mechanism was proposed to rationalize the reaction procedure.
科研通智能强力驱动
Strongly Powered by AbleSci AI