自动氧化
激进的
化学
醌
半醌
光化学
溶剂
有机化学
作者
Paul Ashworth,W. T. Dixon
出处
期刊:Journal of the Chemical Society
日期:1972-01-01
卷期号: (9): 1130-1130
被引量:38
摘要
The autoxidation of hydroquinones and quinones in strongly alkaline solution gives rise to radical intermediates other than the expected semiquinones. These ‘secondary’ radicals, which are derived from 1,2,4-trihydroxybenzene, can be characterised by means of e.s.r. spectroscopy. Different isomeric radicals may be formed, depending on the solvent, and apparently these may reduce any excess of quinone present to the corresponding semiquinone.
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