二硫化碳
化学
亚甲基
硫代磷酸盐
碳负离子
溶剂
烟气脱硫
硫化钠
亚甲蓝
碳纤维
有机化学
光化学
催化作用
复合材料
材料科学
复合数
光催化
作者
Bénédicte Heuzé,Margareth Lemarié,Michel Vazeux,Mihaela Gulea,Serge Masson,Aboubacary Sène,Paul‐Alain Jaffrès,Angelo Alberti,Dante Macciantelli
标识
DOI:10.1080/10426500802715528
摘要
The reaction of carbon disulfide with an excess of sodium dialkylphosphite in an aprotic solvent led to the formation of the carbanion of methylene bisphosphonate and sodium thiophosphate. The mechanistic study of this unexpected reaction, using both 31 P NMR and ESR spectroscopy, suggests the formation of a radical intermediate able to abstract a hydrogen atom from the solvent.
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