电合成
电化学
电极
纳米技术
氧化还原
可再生能源
水溶液
材料科学
生化工程
化学
无机化学
生态学
有机化学
物理化学
工程类
生物
作者
Simone Ciampi,K. Swaminathan Iyer
标识
DOI:10.1016/j.coelec.2022.100992
摘要
Electrochemists and engineers regard adherent gas bubbles as redox-inactive and therefore blocking entities. Adhesion of bubbles at electrodes generally carries an energy penalty. But this is not always the case: bubbles pinned on an electrode surface initiate the oxidation of water-soluble species under conditions where such reactions would normally be considered impossible. Here we critically review the recent literature that is beginning to unveil the novel concept of on-water electrochemistry. Harnessing electrochemical reactivity of the water–gas–electrode interface has the potential to become a game-changer in organic electrosynthesis, accelerating the transition toward a sustainable chemical industry by simplifying the direct integration of renewable electricity into the production of commodity chemicals.
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