脱碳
甲酰胺类
化学
氢胺化
催化作用
甲酰胺
选择性
组合化学
芳基
分子内力
有机化学
烷基
作者
Shaocheng Li,Thayalan Rajeshkumar,Jincheng Liu,Laurent Maron,Xigeng Zhou
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-12-25
卷期号:25 (1): 163-168
被引量:6
标识
DOI:10.1021/acs.orglett.2c03981
摘要
Herein we report the first catalytic decarbonylation and decarbonylative hydroamination of formamides without using additives enabled by a redox-neutral rare earth catalyst. The protocol displays complete N-aryl/alkenyl formamide-selectivity, thus providing a wide variety of creative uses of the N-formylation and N-deformylation method and opening up new prospects for minimizing waste and controlling the required selectivity in amine transformation events.
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