单斜晶系
结晶学
大气温度范围
同步加速器
衍射
晶体结构
X射线晶体学
材料科学
单晶
粉末衍射
三角晶系
相(物质)
化学
物理
热力学
有机化学
核物理学
光学
作者
Jean‐Noël Chotard,Gwenaëlle Rousse,David Rooney,Olivier Mentré,Matthieu Courty,Christian Masquelier
标识
DOI:10.1021/acs.chemmater.5b02092
摘要
The crystal structure of the NASICON Na3V2(PO4)3 phase (NVP) has been investigated as a function of temperature. Combining laboratory and synchrotron X-ray powder diffraction with single crystal X-ray diffraction, we demonstrate the presence of four polymorphs of NVP from 30 to 225 °C. While the high temperature γ-NVP crystallizes in the classical rhombohedral cell (S.G. R3̅c, a = 8.73382(4) Å, c = 21.91438(17) Å), the low temperature α-NVP undergoes a monoclinic distortion (S.G. C2/c, a = 15.1244(6) Å, b = 8.7287(3) Å, c = 21.6143(8) Å, β = 90.163(2)°) together with an ordering of the Na atoms. In the middle temperature range, two incommensurate modulated structures (β- and β′-NVP) are also reported for the first time.
科研通智能强力驱动
Strongly Powered by AbleSci AI