In order to solve the problem that crude oil at low temperature is difficult to demulsify,a complex demulsifier with purification water property at low temperature was synthesized.ARB-01 demulsifier with star-shaped structure was a kind of poly(ethylene oxide)-poly(propylene oxide) block-copolymer with using polyamine as starting agent.PJN-01 was a high efficient cation flocculant which was synthesized by the reaction between amine and epichlorohydrin.CP903DW was prepared through complexing ARB-01 demulsifier and PJN-01 flocculant.It could increase the demulsification efficiency and enhance the speed of dewatering compared with other demulsifiers in the field.