纤维素
降级(电信)
膜
全氟辛酸
电子顺磁共振
材料科学
化学工程
纳米颗粒
可见光谱
羟丙基纤维素
光化学
化学
有机化学
纳米技术
复合材料
聚合物
物理
工程类
计算机科学
电信
生物化学
光电子学
核磁共振
作者
Jinhao Gao,Wenqiang Chen,Hang Shi,Li Z,Liming Jing,Chen Hou,Jian‐Zhi Wang,Yang Wang
标识
DOI:10.1016/j.surfin.2022.102302
摘要
Co3O4@Fe3O4/cellulose membrane was synthesized by coating rod-like MOF-derived Fe3O4 with Co3O4 nanoparticles and blending with cellulose solution, further applied in the visible light-driven photo-Fenton system for perfluorooctanoic acid (PFOA) degradation. In the H2O2/membrane/visible light system, the Electron paramagnetic resonance (EPR) analysis and scavenger experiment results suggested that PFOA degradation was a co-dependent mechanism via photogenerated electrons, photogenerated holes (h+) and various radical species, rather than a single active constituent. Co3O4@Fe3O4/cellulose membrane showed outstanding degradation performance, stability and recyclability under optimal conditions. Compared with pure Fe3O4 or Co3O4 nanoparticles, the Co3O4@Fe3O4/cellulose membrane can degrade around 94.5% PFOA within 180 min in reaction system, and the leached Fe and Co was only 0.05 and 0.49 ppm, respectively. Moreover, Co3O4@Fe3O4/cellulose was reused by rinsing with ultra-pure water and the degradation capacity was still 80.4% after five cycles. The degradation pathway of PFOA also was proposed based on UHPLC-MS analysis.
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