Dual-bed Catalytic System for the Selective Reduction of NOx with Propene

For the removal of NOx from exhausts containing excess oxygen, the selective catalytic reduction of NOx using hydrocarbons (HC-SCR) is highly interesting, especially for car applications (lean deNOx) [1]. Two types of HC-SCR catalysts can be distinguished. High-temperature catalysts operate at temperatures above 573 K, showing moderate activity, and (mostly) low heat and poison resistance, but high N2 selectivity. Low-temperature catalysts, usually based on Pt, operate between 473 and 573 K, showing opposite features: very high activity, as well as heat and poison resistance, and a low N2 selectivity by forming N2O. Our strategy for developing an active and stable deNOx system without N2O emission is the implementation of a separate catalytic function for N2O removal as a second stage.