电解质
电解
循环伏安法
无机化学
材料科学
电极
电化学
电容
水溶液
钠
化学
比能量
储能
插层(化学)
化学工程
分析化学(期刊)
色谱法
冶金
有机化学
功率(物理)
物理
物理化学
工程类
量子力学
作者
Jay Whitacre,Amul Tevar,Shyam Sharma
标识
DOI:10.1016/j.elecom.2010.01.020
摘要
Here we demonstrate Na4Mn9O18 as a sodium intercalation positive electrode material for an aqueous electrolyte energy storage device. A simple solid-state synthesis route was used to produce this material, which was then tested electrochemically in a 1 M Na2SO4 electrolyte against an activated carbon counter electrode using cyclic voltammetry and galvanostatic cycling. Optimized Na4Mn9O18 was documented as having a specific capacity of 45 mAh/g through a voltage range of 0.5 V, or an equivalent specific capacitance of over 300 F/g. With the proper negative:positive electrode mass ratio, energy storage cells capable of being charged to at least 1.7 V without significant water electrolysis are documented. Cycling data and rate studies indicate promising performance for this unexplored low-cost positive electrode material.
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