Corrosion resistance and mechanism of micro-nano structure super-hydrophobic surface prepared by laser etching combined with coating process

腐蚀 材料科学 接触角 涂层 超疏水涂料 镁合金 微观结构 复合材料 冶金 表面能
作者
Qianqian Zhang,Huichen Zhang
出处
期刊:Anti-corrosion Methods and Materials [Emerald Publishing Limited]
卷期号:66 (3): 264-273 被引量:27
标识
DOI:10.1108/acmm-07-2018-1964
摘要

Purpose The purpose of this paper is to evaluate the effect of micro-nano mixed super-hydrophobic structure on corrosion resistance and mechanism of magnesium alloys. Design/methodology/approach A super-hydrophobic surface was fabricated on AZ91 and WE43 magnesium alloys by laser etching and micro-arc oxidation (MAO) with SiO 2 nanoparticles coating and low surface energy material modification. The corrosion resistance properties of the prepared super-hydrophobic surfaces were studied based on polarization curves and immersion tests. Findings Compared with bare substrates, the corrosion resistance of super-hydrophobic surfaces was improved significantly. The corrosion resistance of super-hydrophobic surface is related to micro-nano composite structure, static contact angle and pretreatment method. The more uniform the microstructure and the larger the static contact angle, the better the corrosion resistance of the super-hydrophobic surface. The corrosion resistance of super-hydrophobic by MAO is better than that of laser machining. Corrosion of super-hydrophobic surface can be divided into air valley action, physical shielding, pretreatment layer action and substrate corrosion. Originality/value The super-hydrophobic coatings can reduce the contact of matrix with water so that a super-hydrophobic coating would be an effective way for magnesium alloy anti-corrosion. Therefore, the corrosion resistance properties and mechanism of the prepared super-hydrophobic magnesium alloys were investigated in detail.
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