Advancement in conductive cotton fabrics through in situ polymerization of polypyrrole-nanocellulose composites

纳米纤维素 聚吡咯 材料科学 复合材料 聚合 纤维素 导电聚合物 原位聚合 化学工程 涂层 复合数 聚合物 工程类
作者
A. Hebeish,S. Farag,S. Sharaf,Tharwat I. Shaheen
出处
期刊:Carbohydrate Polymers [Elsevier BV]
卷期号:151: 96-102 被引量:82
标识
DOI:10.1016/j.carbpol.2016.05.054
摘要

Current research was undertaking with a view to innovate a new approach for development of conductive - coated textile materials through coating cotton fabrics with nanocellulose/polypyrrole composites. The study was designed in order to have a clear understanding of the role of nanocellulose as well as modified composite thereof under investigation. It is anticipated that incorporation of nanocellulose in the pyrrole/cotton fabrics/FeCl3/H2O system would form an integral part of the composites with mechanical, electrical or both properties. Three different nanocellulosic substrates are involved in the oxidation polymerization reaction of polypyrrole (Ppy) in presence of cotton fabrics. Polymerization was subsequently carried out by admixing at various ratios of FeCl3 and pyrrole viz. Ppy1, Ppy2 and pp3. The conductive, mechanical and thermal properties of cotton fabrics coated independently with different nanocellulose/polypyrrole were investigated. FTIR, TGA, XRD, SEM and EDX were also used for further characterization. Results signify that, the conductivity of cotton fabrics increases exponentially with increasing the dose of pyrrole and oxidant irrespective of nanocellulose substrate used. While, the mechanical properties of cotton fabrics are not significantly affected by the oxidant treatment.
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