Boosting Electrochemical Water Oxidation on NiFe (oxy) Hydroxides by Constructing Schottky Junction toward Water Electrolysis under Industrial Conditions

Abstract The practical deployment of promising NiFe‐based oxygen evolution reaction (OER) electrocatalysts is heavily limited due to the constrain in both stability and activity under industrial conditions. Herein, a 3D free‐standing NiFe(oxy)hydroxide‐based electrode with Schottky junction is constructed, in which NiFe(oxy)hydroxide (NiFe(OH) x ) nanosheets are chemically assembled on the top of metal‐like Ni 3 S 2 scaffold that are in situ formed on commercial Ni mesh. Such an assembly enhances the binding strength of each components, promotes the charge transfer across the interfaces, and modulates the electronic and nanostructural features of NiFe(OH) x . Consequently, the electrode delivers current densities of as high as 500 and 1000 mA cm −2 for OER at overpotentials of only 248 and 270 mV with long‐term stability in 1 m KOH. When it was paired with a NiMo hydrogen evolution cathode in a practical two‐electrode system, a current density of 1000 mA cm −2 is achieved at a low cell voltage of ≈1.61 V at 80 °C in 30% KOH without losing performance for at least 1500 h. This is the best performance reported thus far for alkaline water electrolysis under industrial conditions, demonstrating its great potential for practical applications.