Advances in the Design of 3D‐Structured Electrode Materials for Lithium‐Metal Anodes

Abstract Although the lithium‐metal anode (LMA) can deliver a high theoretical capacity of ≈ 3860 mAh g −1 at a low redox potential of − 3.040 V (vs the standard hydrogen electrode), its application in rechargeable batteries is hindered by the poor Coulombic efficiency and safety issues caused by dendritic metal growth. Consequently, careful electrode design, electrolyte engineering, solid‐electrolyte interface control, protective layer introduction, and other strategies are suggested as possible solutions. In particular, one should note the great potential of 3D‐structured electrode materials, which feature high active specific surface areas and stereoscopic structures with multitudinous lithiophilic sites and can therefore facilitate rapid Li‐ion flux and metal nucleation as well as mitigate Li dendrite formation through the kinetic control of metal deposition even at high local current densities. This progress report reviews the design of 3D‐structured electrode materials for LMA according to their categories, namely 1) metal‐based materials, 2) carbon‐based materials, and 3) their hybrids, and allows the results obtained under different experimental conditions to be seen at a single glance, thus being helpful for researchers working in related fields.