MOF-Mediated Interfacial Polymerization to Fabricate Polyamide Membranes with a Homogeneous Nanoscale Striped Turing Structure for CO2/CH4 Separation

Control of the surface morphology of polyamide membranes fabricated by interfacial polymerization is of great importance in dictating the separation performance. Herein, polyamide membranes with a specific nanoscale striped Turing structure are generated through facile addition of Zr-based metal-organic framework UiO-66-NH₂ in the aqueous triethylenetetramine phase. Interestingly, accompanied by the degradation of UiO-66-NH₂ in aqueous solution, an intermediate complex is in situ formed through the strong interaction between the Zr metal center and the amine group from triethylenetetramine, which can lower amine diffusion and induce a local interfacial reaction, contributing to the generation of a homogeneous nanoscale striped Turing structure. The resulting membranes are used for CO₂/CH₄ gas separation. Compared with the parent polyamide membrane displaying a CO₂/CH₄ selectivity of 43.1 and a CO₂ permeance of 31.5 GPU, the membrane with 0.02 wt % of UiO-66-NH₂ introduced into the aqueous phase shows a higher CO₂/CH₄ selectivity of 58.3, along with a CO₂ permeance of 27.1 GPU. Additionally, when 0.1 wt % of UiO-66-NH₂ is incorporated into the aqueous phase, the membrane exhibits a combination of a higher CO₂/CH₄ selectivity and an enhanced CO₂ permeance in contrast with the parent polyamide membrane.