Anodizing and corrosion behaviour of aluminium

阳极氧化 材料科学 腐蚀 极化(电化学) 氧化物 冶金 阳极 介电谱 电化学 电极 化学 物理化学
作者
Başak Doğru Mert,Birgül Yazıcı,Tunç Tüken,Gülfeza Kardaş,M. Erbil
出处
期刊:Protection of Metals and Physical Chemistry of Surfaces [Pleiades Publishing]
卷期号:47 (1): 102-107 被引量:14
标识
DOI:10.1134/s2070205110051028
摘要

In this study, aluminum was anodized in 0.4 M H 2 SO 4 + 0.145 M H 3 BO 3 solution by means of potentiostatic method. In first step, the most appropriate conditions (anodizing voltage and period) were determined. The voltage-current behavior was investigated between 0 to 30 V and oxide formation potential (15 V) was determined. Then chorono-amperometric measurement was obtained at this potential during 2 hours. Therefore, anodizing process was applied at 15 V between aluminium anode and mild steel cathode. In the second step, the corrosion performance of non-anodized (Al) and anodized samples (Al 2 O 3 ) have been investigated in 3.5% NaCl solution by using electrochemical impedance spectroscopy and polarization techniques. The interface between metal and solution was modeled with the equivalent circuit successfully. The circuit’s elements were calculated with Ivium Soft fitting program. The polarization curves were obtained between −1.8 V and 0.5 V potential ranges. The experimental results proved that the thickness and quality of oxide film was improved with help of anodizing process. Thus the corrosion resistance of anodized aluminum is significantly increased.
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