Fabrication of 3 D Mesoporous Black TiO2/MoS2/TiO2 Nanosheets for Visible‐Light‐Driven Photocatalysis

Abstract A novel 3 D mesoporous black TiO 2 (MBT)/MoS 2 /MBT sandwich‐like nanosheet was successfully fabricated using a facile mechanochemical process combined with an in situ solid‐state chemical reduction approach, followed by mild calcination (350 °C) under an argon atmosphere. The MBT/MoS 2 /MBT exhibits a 3 D sandwich‐like nanosheet structure and heterojunctions are formed at the interfaces between MoS 2 and black TiO 2 . The significantly narrowed band gap of MBT/MoS 2 /MBT is attributed to the introduction of MoS 2 and the formed Ti 3+ species in the frameworks. The visible‐light photocatalytic degradation rate of methyl orange and the hydrogen production rate are as high as 89.86 % and 0.56 mmol h −1 g −1 , respectively. The introduction of MoS 2 and Ti 3+ in the frameworks favors the visible‐light absorption and the separation of photogenerated charges, and the 3 D sandwich‐like heterojunction structure facilitates the transfer of photogenerated charges.