催化作用
纳米颗粒
材料科学
对苯二甲酸二甲酯
纳米技术
化学
有机化学
作者
Ana B. Hungría,Robert Raja,Richard D. Adams,Burjor Captain,John Meurig Thomas,Paul A. Midgley,Vladimir B. Golovko,Brian F. G. Johnson
标识
DOI:10.1002/anie.200600359
摘要
Highly active and selective: A supported Ru5PtSn nanoparticle cluster (the picture shows an axial projection of a tomogram), prepared from the carbonyl cluster [PtRu5(CO)15(μ-SnPh2)(μ6-C)], is an excellent catalyst in the single-step hydrogenation of dimethyl terephthalate to cyclohexanedimethanol under mild conditions (100 °C, 20 bar H2).
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