催化作用
氧还原反应
燃料电池
质子交换膜燃料电池
膜
化学
离子交换
氧气
离子
氧还原
还原(数学)
化学工程
无机化学
电化学
电极
有机化学
物理化学
生物化学
几何学
数学
工程类
作者
Wen Huang,Jiawei Zhang,Guoqiang Deng,Guangcan Zhu,Yaohui Chen,Chenxi Xu,Jigui Cheng
标识
DOI:10.1021/acsaem.4c03250
摘要
Anion exchange membrane fuel cells (AEMFCs) have emerged as a promising clean energy technology due to their high efficiency and the potential to eliminate the reliance on precious metal catalysts for the oxygen reduction reaction (ORR) at the cathode. Developing highly efficient nonprecious metal catalysts is crucial for enhancing AEMFC performance. In this study, we report a Co–S–N–C@MXene catalyst through sulfur doping and support loading. This catalyst demonstrates exceptional ORR activity, achieving a half-wave potential ( E 1/2 ) of 0.881 V. After 10,000 cycles of cyclic voltammetry (CV) testing, the E 1/2 showed a minimal decline of only 14 mV, demonstrating excellent durability. Moreover, the AEMFC based on the catalyst achieved a peak power density of 466 mW cm –2 .
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