芴
亲核细胞
荧光
水杨醛
氰化物
光化学
转身(生物化学)
化学
离子
含时密度泛函理论
活体细胞成像
检出限
组合化学
分子
高分子化学
无机化学
席夫碱
有机化学
光学
催化作用
细胞
色谱法
物理
生物化学
聚合物
作者
Manas Kumar Bera,Chanchal Chakraborty,Pradeep K. Singh,Chandan Sahu,Kaushik Sen,Samir K. Maji,Abhijit K. Das,Sudip Malik
摘要
A new salicylaldehyde appended fluorene-based chemodosimeter (FSal) has been designed by taking consideration of the special nucleophilicity of cyanide ion. FSal shows selective affinity towards CN− over other anions (namely F−, Br−, NO3−, ClO4−, N3−, H2PO4−, AcO−, I−, Cl−, and NO2−) through turn-on fluorescence with a minimum detection limit of 0.06 ppm. The turn-on fluorescence of the FSal–CN complex resulting from hampering ESIPT is also supported by DFT and TDDFT calculations. Biological compatibility and live cell imaging of this unique probe have also been explored.
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