拉曼光谱
硫化物
金属
漆酶
表面增强拉曼光谱
材料科学
光谱学
纳米技术
化学工程
化学
拉曼散射
冶金
生物化学
酶
工程类
光学
物理
量子力学
作者
Sisi Wen,Wenji Jiang,Yumei Yang,Liang Shang,Xu Wang,Bing Zhao,Wei Song
标识
DOI:10.1021/acs.jpcc.4c00844
摘要
Transition metal sulfides (TMS) exhibit unique attributes such as high electron mobility, excellent charge transfer ability, narrow band gap, and large surface area, which makes them particularly attractive for use in surface-enhanced Raman spectroscopy (SERS) and as catalysts applications. In this study, we prepared NiCo2S4 TMS nanosheets through a hydrothermal process. These nanosheets display outstanding SERS activity, which is attributed to their exceptional charge transfer interactions with crystal violet (CV). In addition, NiCo2S4 nanosheets display excellent laccase-like activity. Density functional theory (DFT) calculations further reveal that NiCo2S4–O2 exhibits a low adsorption energy and pronounced laccase-like catalytic performance. Furthermore, the NiCo2S4 nanosheets show great potential for the oxidation and detection of various catechin molecules. Consequently, the NiCo2S4 nanosheets exhibit immense potential in various applications, including SERS analysis and detection, laccase-like antibacterial properties, and the degradation of environmental pollutants.
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