Soluble and Perfluorinated Polyelectrolyte for Safe and High‐Performance Li−O2 Batteries

Abstract The severe performance degradation of high‐capacity Li−O 2 batteries induced by Li dendrite growth and concentration polarization from the low Li + transfer number of conventional electrolytes hinder their practical applications. Herein, lithiated Nafion (LN) with the sulfonic group immobilized on the perfluorinated backbone has been designed as a soluble lithium salt for preparing a less flammable polyelectrolyte solution, which not only simultaneously achieves a high Li + transfer number (0.84) and conductivity (2.5 mS cm −1 ), but also the perfluorinated anion of LN produces a LiF‐rich SEI for protecting the Li anode from dendrite growth. Thus, the Li−O 2 battery with a LN‐based electrolyte achieves an all‐round performance improvement, like low charge overpotential (0.18 V), large discharge capacity (9508 mAh g −1 ), and excellent cycling performance (225 cycles). Besides, the fabricated pouch‐type Li–air cells exhibit promising applications to power electronic equipment with satisfactory safety.