A facile method for preparing the CeMnO3 catalyst with high activity and stability of toluene oxidation: The critical role of small crystal size and Mn3+-Ov-Ce4+ sites

Volatile organic compounds (VOCs) cause severe environmental pollution and are potentially toxic to humans who have no defense against exposure. Catalytic oxidation of these compounds has thus become an interesting research topic. In this study, microcrystalline CeMnO3 catalysts were prepared by a precipitant-concentration-induced strategy and evaluated for the catalytic oxidation of toluene/benzene. The effect of crystal size on catalytic performance was confirmed by XRD, TEM, N2 adsorption-desorption, XPS, Raman, H2-TPR, and TPSR. The CeMnO3 catalyst with more Mn3+-Ov-Ce4+ active sites exhibited enhanced VOCs catalytic oxidation performance, lowest active energy, and highest turnover frequency, which was attributed to its larger surface area, lower crystal size, higher low-temperature reducibility, and presence of more oxygen defects. In-situ FTIR results suggested more oxygen vacancies can profoundly promote the conversion of benzoate to maleate species, the rate-determining step of toluene oxidation. The work provides a convenient and efficient strategy to prepare single-metal or multi-metal oxide catalysts with smaller crystal sizes for VOC oxidation or other oxidation reactions.