Adsorption and photocatalytic applications of porphyrin-based materials for environmental separation processes: A review

As society progresses and industrializes, the issue of water pollution, caused by a wide array of organic and inorganic pollutants, poses significant risks to both human well-being and the environment. Given its distinctive characteristics, water pollution has become a paramount concern for society, necessitating immediate attention. Numerous studies have been conducted on wastewater treatment, primarily focusing on two key approaches: adsorption and photocatalytic degradation. Adsorption offers unparalleled advantages, including its simplicity, high removal efficiency, and cost-effectiveness. Conversely, photocatalysis harnesses abundant, clean, and non-polluting sunlight, addressing the critical issue of energy scarcity. Porphyrins, which are macrocyclic tetrapyrrole derivatives found widely in nature, have attracted growing interest in recent years. These lipophilic pigments exhibit remarkable chemical stability and have retained their major structural features for up to 1.1 billion years. As such, they are considered vital indicators of life and have been extensively studied, from the remnants of extinct organisms to gain insights into the principles of evolution. Porphyrins are often associated with a central metal ion within their ring system and can be modified through various substituents, including additional rings or ring opening, resulting in a wide range of functionalities. This comprehensive review summarizes recent advancements in the field of porphyrins. It begins by introducing the structures and preparation methods of porphyrins. Subsequently, it delves into notable applications of porphyrins in the context of pollutant adsorption in water and their environmentally friendly photocatalytic degradation.