Enhancing the physicochemical properties of nickel cobaltite catalyst for oxygen evolution reaction in anion exchange membrane water electrolyzers

Abstract Hierarchical hollow urchin-like nickel cobaltite (NiCo 2 O 4 ) was synthesized using a two-step hydrothermal method. The effects of metal composition and surfactant addition on the morphology, structure, and electrochemical performance toward oxygen evolution reaction (OER) were investigated. The addition of cetyltrimethylammonium bromide (CTAB) reduced particle aggregation, resulting in a higher electrochemical active surface area and electrical conductivity. Lowering the Ni content from 1.0 to 0.25 did not alter the morphology and structure of the product to any extent. However, the crystallite size slightly increased. Among the spinels with different Ni and Co compositions, NiCo 2 O 4 exhibited a superior OER electrocatalytic activity, achieving a 380 mV overpotential at 10 mA/cm 2 current density. It also delivered a good performance in an anion exchange membrane water electrolyzer (AEMWE) using 1 M NaOH at 60 °C, reaching a current density of about 420 mA/cm 2 at a cell voltage of 1.95 V.