电位滴定法
化学
石墨氮化碳
电位传感器
氯化物
电极
无机化学
检出限
参比电极
离子选择电极
氢醌电极
氯化银
分析化学(期刊)
电化学
选择性
色谱法
物理化学
有机化学
催化作用
光催化
作者
Taher Alizadeh,Faride Rafiei,Maedeh Akhoundian
出处
期刊:Talanta
[Elsevier]
日期:2022-01-01
卷期号:237: 122895-122895
被引量:8
标识
DOI:10.1016/j.talanta.2021.122895
摘要
In this research, AgCl anchored graphitic carbon nitride (g-C3N4) was introduced as a novel potentiometric sensing element. A g-C3N4/AgCl-modified carbon paste electrode (CPE) was fabricated and used as an outstandingly selective potentiometric sensor to determine Cl- in water samples. The g-C3N4/AgCl nanocomposite was characterized with SEM, XRD and FT-IR techniques. It was demonstrated that, the incorporation of 5% of g-C3N4/AgCl, as a chloride ionophore in a CPE, results in a stable potential response of the electrode to chloride ion. The Nernstian slope of the electrode response was 55.4 (±0.3) mVdecade-1, over a wide linear concentration range of 1 × 10-6-1 × 10-1 mol L-1 and the detection limit of the electrode was estimated to be 4.0 × 10-7 mol L-1. The g-C3N4/AgCl-modified CPE electrode provided fast response time and long-term stability (more than 2 months) while the potential interfering ions such as I-, Br-, and CN- showed no significant effect on the potential response. Since these interfering ions affected the response of the CPE electrode, modified with AgCl, highlighting the interesting effect of g-C3N4 on the sensor performance. This innovative electrode was shown to be a sensitive and accurate sensor for chloride ion content estimation in water samples.
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