Hyperbranched Polyborate: A Non‐conjugated Fluorescent Polymer with Unanticipated High Quantum Yield and Multicolor Emission

Non-conjugated fluorescent polymers have attracted great attention due to their excellent biocompatibility and environmental friendliness. However, it remains a huge challenge to obtain a polymer with high fluorescence quantum yield (QY) and multicolor emission simultaneously. Herein, we reported three kinds of nonaromatic hyperbranched polyborates (P1-P3) with multicolor emission, surprisingly, P2 also exhibits an unanticipated high QY (54.1 %). The natural bond orbital (NBO) analysis and density functional theory (DFT) calculation results revealed that the synergistic effect of rigid BO₃ planar and flexible carbon chain, as well as the through-space dative bond in supramolecular aggregate, were the key factors contributing to the ultrahigh QY of P2. Moreover, the applications of P2 in Fe³⁺ ions detection and cell imaging were also investigated. This work provides a new perspective for designing non-conjugated fluorescent polymers with both high QY and multicolor emission.