胺化
化学
铈
键裂
催化作用
劈理(地质)
光催化
表面改性
光化学
氯化物
有机化学
高分子化学
组合化学
材料科学
复合材料
物理化学
断裂(地质)
作者
Jingjing Guo,Anhua Hu,Yilin Chen,Jianfeng Sun,Haoming Tang,Zhiwei Zuo
标识
DOI:10.1002/anie.201609035
摘要
A general strategy for the cleavage and amination of C-C bonds of cycloalkanols has been achieved through visible-light-induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C-C bond cleavage and functionalization of unstrained secondary cycloalkanols.
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