球磨机
酰化
催化作用
电子转移
化学
溶剂
脱羧
有机化学
材料科学
组合化学
复合材料
作者
Yu He,Gefei Wang,Wenbo Hu,Diandian Wei,Jiajia Jia,Heng Li,Bingxin Yuan
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2023-01-11
卷期号:11 (3): 910-920
被引量:9
标识
DOI:10.1021/acssuschemeng.2c04720
摘要
The first piezochemically driven decarboxylative coupling of the C–H bond was developed. The agitation of BaTiO3 via ball milling converts mechanical energy into electrical potential, leading to the production of a benzoyl radical via a single-electron transfer pathway analogous to the photocatalytic reaction. This mechanoredox BaTiO3 catalytic strategy to synthesize C3-acylated quinoxalin-2(1H)-ones requires no solvent, a short reaction time, and simple handling skills, exhibiting promising potential in large-scale chemical manufacturing.
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