化学
烷基
二硫代氨基甲酸盐
催化作用
有机化学
组合化学
硫化氢
电化学
硫化物
基质(水族馆)
硫黄
海洋学
物理化学
电极
地质学
作者
Xiaoying Li,Tian-Cheng Cai,Mengxue Zhu,Yuxuan Liu,Jingjing Xia,Jingzhong Xie,Lixin Wen,Qingwen Gui,Yan Yin
标识
DOI:10.1021/acs.joc.3c01017
摘要
Dithiocarbamates synthesis is extremely important in plenty of biomedical and agrochemical applications, especially fungicide development, but remains a great challenge. In this work, we have successfully developed a multicomponent reaction protocol to convert H2S into S-alkyl dithiocarbamates under constant current conditions. No additional oxidants nor additional catalysts are required, and due to mild conditions, the reactions display a broad substrate scope, including varieties of thiols or disulfides.
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