2D Transition Metal Chalcogenides (TMDs) for Electrocatalytic Hydrogen Evolution Reaction: A Review

Since the MoS₂ synthesis, the family of two-dimensional transition metal chalcogenides (TMDs) have been intensively explored theoretically and experimentally. TMDs endowed with adjustable electronic, physical and chemical properties lead to increasing interest in the application of energy storage, molecule detection and catalysis. In the mini review, we present a forward-looking summary of 2D TMDs in hydrogen evolution electrocatalysis, including synthesis methods, hydrogen evolution performance, and optimization strategies. This review will deepen the fundamental understanding of the physical-chemical properties of TMDs with different phases and contribute unveil the universal principle among electronic configuration, atomic arrangement, physical and chemical property for the material design.