解吸
氢
镁
氢化物
扩散
化学
热导率
限制
氢化镁
分析化学(期刊)
活化能
电导率
热脱附
吸收(声学)
材料科学
无机化学
热力学
冶金
物理化学
复合材料
吸附
有机化学
工程类
物理
机械工程
作者
Julien Lang,Mitch Eagles,Mark S. Conradi,Jacques Huot
标识
DOI:10.1016/j.jallcom.2013.08.126
摘要
In this paper, the investigation of the rate limiting steps in hydrogen absorption and desorption of cold rolled magnesium hydride is reported. Absorption and desorption curves were made at different temperatures with constant driving force. Results show that the rate limiting step of the reactions of magnesium with hydrogen does not change with temperature. After cold rolling, hydrogen absorption is diffusion controlled, while the desorption process is three dimensional growth of existing nuclei. NMR measurements are also reported; there is no increase in the rate of hydrogen diffusive motions in the cold rolled material, compared to bulk. The effect of rolling and ball milling on thermal conductivity was also investigated.
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