水溶液
纤维素
材料科学
化学工程
朗缪尔吸附模型
高分子科学
朗缪尔
弗伦德利希方程
吸附
傅里叶变换红外光谱
核化学
羧甲基纤维素
化学
高分子化学
有机化学
工程类
作者
Yunhua Li,Hongxiang Zhu,Cunzhi Zhang,Cheng Meixiao,Hui He
出处
期刊:Cellulose
[Springer Nature]
日期:2018-06-12
卷期号:25 (8): 4757-4769
被引量:34
标识
DOI:10.1007/s10570-018-1868-2
摘要
A novel PEI-grafted magnetic cellulose (Fe3O4/MCC-PEI) with high amino density was prepared by grafting PEI onto the surface of magnetic cellulose in NaOH/urea aqueous solvent. The embedding of Fe3O4 into cellulose provided excellent magnetic responsiveness for recycling the adsorbent in the magnetic field. The adsorbent for Cr(VI) removal from aqueous solution overcame the disadvantages of adsorbent like difficult recycling, poor regeneration performance and low removal rate at low Cr(VI) concentration. Therefore, the as-prepared Fe3O4/MCC-PEI showed high Cr(VI) adsorption capacity (198.8 mg/g) which could achieve adsorption equilibrium within 10 min, and the removal rate could reach 100% at low Cr(VI) concentration (less than 1.0 mg/L), demonstrating that the high amino density (7.85 mmol/g) and magnetic responsiveness of the adsorbent can greatly promote adsorption capacity and removal efficiency. The adsorbent also showed promising regeneration performance, and the adsorption capacity remained above 96% after six cycles.
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