A New Hydrothermal Route for Synthesis of Molybdenum Disulphide Nanorods and Related Nanostructures

A simple approach to prepare nanorods of Molybdenum Disulphide (MoS 2 ) using hydrothermal method by reacting aqueous solutions of (NH 4 ) 6 Mo 7 O 24 · 4 H 2 O, C 2 H 4 NS and Na 2 S 2 O 4 at 190 °C for 24 h is described. The hydrothermal product has been subsequently subjected to the thermal treatment in nitrogen atmosphere at 675 °C for 6 h and characterized. X-ray diffraction (XRD) of the hydrothermal product indicated the formation of MoS 2 relatively with much lower crystallinity compared to when it thermally treated. Energy dispersive analysis (EDX) was done to know the chemical composition of the product. TEM showed onset growth of MoS 2 nanorods within the hydrothermal products itself and in thermally treated products it was prominent with the diameter of the nanorods ranging between 10–20 nm. Photoluminescence spectra MoS 2 nanorods shows an intense absorbance at around 429 nm. TGA of the MoS 2 nanorods in air and nitrogen atmosphere has also been studied. The extent of formation of MoS 2 from the precursors obtained at 190 °C for duration of 12, 18, and 24 h and annealed at 675 °C for 6 h under nitrogen atmosphere is also demonstrated based on XRD data.