A UV‐Resistant Heterogeneous Wettability‐Patterned Surface

Abstract Preparing UV‐resistant heterogeneous wettability patterns is critical for the practical application of surfaces with heterogeneous wettability. However, combining UV‐resistant superhydrophobic and superhydrophilic materials on heterogeneous surfaces is challenging. Inspired by the structure of cell membranes, a UV‐resistant heterogeneous wettability‐patterned surface (UPS) is designed via laser ablation of the coating of multilayer structures. UV‐resistant superhydrophobic silica patterns can be created in situ on surfaces covered with superhydrophilic TiO 2 nanoparticles. The UV resistance time of the UPS with a TiO 2 ‐based surface is more than two orders of magnitude higher than that obtained with other surface molecular modification methods that require a mask. The cell‐membrane‐like structure of the UPS regulates the migration of internal siloxane chain segments in the hydrophilic and hydrophobic regions of the surface. The UPS enables efficient patterning of functional materials under UV irradiation, controlling the wetting behavior of liquids in open‐air systems. Furthermore, its heterogeneous wettability remains stable even after 50 h of intense UV irradiation (365 nm, 500 mW cm −2 ). These UV‐resistant heterogeneous wettability patterned surfaces will likely be applied in microfluidics, cell culture, energy conversion, and water collection in the future.