Heterostructures of Ti3C2Tx–Bi2Te3 Nanosheets as Saturation Absorbers for Femtosecond Pulse Generation

Two-dimensional (2D) nanomaterials have immense potential in ultrafast laser applications due to their excellent optical characteristics. However, the low modulation depth of individual materials obstructs enhancement of the laser pulse output, which limits the application of individual materials. Therefore, we prepared a Ti3C2Tx–Bi2Te3 vertical heterostructure (TB-VHS) using ultrasound-assisted methods to overcome the limitations of the individual materials. Various functional groups in Ti3C2Tx lead to the formation of heterogeneous structures of different systems at the interface between Ti3C2Tx and Bi2Te3. The transfer of strong interlayer carriers exhibits excellent nonlinear-optical properties. The modulation depth of TB-VHS was ∼8.2 times that of Ti3C2Tx and 2.5 times that of Bi2Te3. Furthermore, TB-VHS was used as a saturable absorber (SA) to realize stable conventional soliton pulses with a pulse duration of 547 fs under 1557.76 nm. Our results indicate that Ti3C2Tx–Bi2Te3 heterostructures are promising SAs for pulsed-laser applications.