Tunable mono- or 1,1-double Heck-type coupling reaction of unconjugated amido-alkenes with remote benzylic C(sp 3 )–H of N -fluorobenzamides

A tunable mono- or unprecedented 1,1-double Heck-type cross-coupling of unconjugated amido-alkenes directed by the remote C(sp 3 )–H of N -fluorobenzamides was developed, and a variety of polysubstituted alkenes was obtained in good yields.