反铁磁性
凝聚态物理
铁磁性
磁化
电阻率和电导率
磁性
磁矩
中子衍射
化学
材料科学
磁场
物理
结晶学
晶体结构
量子力学
作者
J.M. Longo,P. M. Raccah,John B Goodenough
摘要
Magnetization measurements of SrRuO3 and CaRuO3 confirm that SrRuO3 is ferromagnetic with TC = (160±5) °K and that CaRuO3 has antiferromagnetic exchange interactions dominant. They further identify in CaRuO3 a Néel temperature TN = (110±10) °K and parasitic ferromagnetism below TN having a σ0 = (3.2±0.4) × 10−2 emu/g at 4.2°K. High-field (to 125 kOe) magnetization and neutron-diffraction data for SrRuO3 are consistent with a reduced spontaneous ferromagnetic moment μ0 = (1.4±0.4) μB and no ordered antiferromagnetic component. Resistivity measurements confirm a low resistivity (ρ<10−3Ω·cm) at room temperature having a metallic temperature coefficient. It is concluded that both compounds represent spontaneous collective-electron magnetism and that the reduced moment of SrRuO3 is due to holes in both the up-spin and down-spin bands. Antiferromagnetic CaRuO3 is predicted to have narrower ``4d'' bands.
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